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A study of particle size distributions was conducted on a Cummins M11 1995 engine using the Scanning Mobility Particle Sizer (SMPS) instrument in the baseline and downstream of the Catalyzed Particulate Filter (CPF). Measurements were made in the dilution tunnel to investigate the effect of primary dilution ratio and mixture temperature on the nuclei and accumulation mode particle formation. Experiments were conducted at two different engine modes namely Mode 11 (25% load - 311 Nm, 1800 rpm) and Mode 9 (75% load - 932 Nm, 1800 rpm). The nanoparticle formation decreased with increasing dilution ratios for a constant mixture temperature in the baseline as well as downstream of the CPF II for Mode 11 condition. At Mode 9 condition in the baseline, the dilution ratio had a little effect on the nanoparticle formation, since the distribution was not bimodal and was dominated by accumulation mode particles.

A model for calculating the trap pressure drop, particulate mass inside the trap and various particulate and trap properties was developed using the steady-state data and the theory developed by Konstandopoulos & Johnson, 1989. Changes were made with respect to the calculation of clean pressure drop, particulate layer porosity and the particulate layer permeability. This model was validated with the data obtained from the steady-state data run with different traps supplied by Corning Inc. The data were collected using the 1988 Cummins L-10 heavy-duty diesel engine using No.2 low sulfur diesel fuel. The three different traps were EX 80 (100 cell density), EX 80 (200 cell density) and EX 66 (100 cell density) all with a 229 mm diameter and 305 mm length. These traps were subjected to different particulate matter loadings at different speeds. The traps were not catalyzed.

Various measurement techniques were employed to quantify sulfuric acid deposition levels and concentration of sulfuric acid in the condensate from the recirculated exhaust gas heat exchanger of a 1995 Cummins M11 heavy-duty diesel engine. Methods employed included a modified version of the sulfur species sampling system developed by Kreso et al. (1)*, rinsing the heat exchanger, and experiments employing a condensate collection device (CCD). The modified sampling system was applied to the inlet and outlet of the heat exchanger in order to quantify the changes in various sulfur compounds. Doped sulfur fuel (3300 to 4000 ppm S) was used to increase the concentrations of the various oxides of sulfur (SOx). These tests were performed at mode 9 of the old EPA 13-mode test cycle (1800 RPM, 932N*m) with 17-20% exhaust gas recirculation (EGR) at two EGR outlet temperatures: 160°C and 103°C.

The Vehicle Engine Cooling System Simulation (VECSS) computer code has been developed at the Michigan Technological University to simulate the thermal response of the cooling system of an on-highway heavy duty diesel powered truck under steady and transient operation. This code includes an engine cycle analysis program along with various components for the four main fluid circuits for cooling air, cooling water, cooling oil, and intake air, all evaluated simultaneously. The code predicts the operation of the response of the cooling circuit, oil circuit, and the engine compartment air flow when the VECSS is operated using driving cycle data of vehicle speed, engine speed, and fuel flow rate for a given ambient temperature, pressure and relative humidity.

The Vehicle Engine Cooling System Simulation (VECSS) computer code has been developed at the Michigan Technological University to simulate the thermal response of a cooling system for an on-highway heavy duty diesel powered truck under steady and transient operation. In Part 1 of this research, the code development and verification has been presented. The revised and enhanced VECSS (version 8.1) software is capable of simulating in real-time a Freightliner FLD 120 truck with a Detroit Diesel Series 60 engine, Behr McCord radiator, Allied signal / Garrett Automotive charge air cooler and turbocharger, Kysor DST variable speed fan clutch, DDC oil and coolant thermostat. Other cooling system components were run and compared with experimental data provided by Kysor Cooling Systems. The experimental data were collected using the Detroit Diesel Electronic Control's (DDEC) Electronic Control Module (ECM) and the Hewlett Packard (HP) data acquisition system.

A model for calculating the trap pressure drop, various particulate properties, filtration characteristics and trap temperatures was developed during the steady-state and transient cycles using the theory originated by Opris and Johnson, 1998. This model was validated with the data obtained from the steady-state cycles run with an IBIDEN SiC diesel particulate filter. To evaluate the trap experimental filtration efficiency, raw exhaust samples were taken upstream and downstream of the trap. A trap scaling and equivalent comparison model was developed for comparing different traps at the same volume and same filtration area. Using the model, the trap pressure drop data obtained from different traps were compared equivalently at the same trap volume and same filtration area. The pressure drop performance of the IBIDEN SiC trap compared favorably to the previously tested NoTox SiC and the Cordierite traps.

To meet future NO, heavy-duty diesel emissions standards, exhaust gas recirculation (EGR) technology is likely to be used. To improve fuel economy and further lower emissions, the recirculated exhaust gas needs to be cooled, with the possibility that cooling of the exhaust gas may form sulfuric acid condensate in the EGR cooler. This corrosive condensate can cause EGR cooler failure and consequentially result in severe damage to the engine. Both a literature review and a preliminary experimental study were conducted. In this study, a manually controlled EGR system was installed on a 1995 Cummins Ml l-330E engine which was operated at EPA mode 9* (1800 rpm and 75% load). The Goksoyr-Ross method (1)** was used to measure the particle-phase sulfate and vapor-phase H2SO4 and SO2 at the inlet and outlet locations of the EGR cooler, obtaining H2SO4 and SO2 concentrations. About 0.5% of fuel sulfur in the EGR cooler was in the particle-phase.

The effects of exhaust gas recirculation (EGR) on heavy-duty diesel emissions were studied at two EPA steady-state operating conditions, old EPA mode 9* (1800 RPM, 75% Load) and old EPA mode 11 (1800 RPM, 25% Load). Data were collected at the baseline, 10% and 16% EGR rates for both EPA modes. The study was conducted using a 1995 Cummins M11-330E heavy-duty diesel engine and compared to the baseline emissions from the Cummins 1988 and 1991 L10 engines. The baseline gas-, vapor- and particle-phase emissions were measured together with the particle size distributions at all modes of operation. The total particulate matter (TPM) and vapor phase (XOC) samples were analyzed for physical, chemical and biological properties. The results showed that newer engines with electronic engine controls and higher injector pressures produce TPM decreases from the 1988 to 1991 to 1995 engines with the solids decreasing more than the soluble organic fraction (SOF) of TPM.

A 2-D CFD model was developed to describe the heat transfer, and reaction kinetics in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state as well as the transient behavior of the flow and heat transfer during the trap regeneration processes. The trap temperature profile was determined by numerically solving the 2-D unsteady energy equation including the convective, heat conduction and viscous dissipation terms. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations (Opris, 1997). The reaction kinetics were described using a discretized first order Arrhenius function. The 2-D term describing the reaction kinetics and particulate matter conservation of mass was added to the energy equation as a source term in order to represent the particulate matter oxidation. The filtration model describes the particulate matter accumulation in the trap.

A 2-D computational model was developed to describe the flow and filtration processes, in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state trap loading, as well as the transient behavior of the flow and filtration processes. The theoretical model includes the effect of a copper fuel additive on trap loading and transient operation. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations. The filtration theory incorporated in the time dependent numerical code included the diffusion, inertia, and direct interception mechanisms. Based on a measured upstream particle size distribution, using the filtration theory, the downstream particle size distribution was calculated. The theoretical filtration efficiency, based on particle size distribution, agreed very well (within 1%) with experimental data for a number of different cases.

A computer simulation of the turbocharged direct- injection diesel engine was developed to enhance the capabilities of the Vehicle Engine Cooling System Simulation (VECSS) developed at Michigan Technological University. The engine model was extensively validated against Detroit Diesel Corporation's (DDC) Series 60 engine data. In addition to the new engine model a charge-air-cooler model was developed and incorporated into the VECSS. A Freightliner truck with a Detroit Diesel's Series 60 engine, Behr McCord radiator, AlliedSignal/Garrett Automotive charge air cooler, Kysor DST variable speed fan clutch and other cooling system components was used for the study. The data were collected using the Detroit Diesel Electronic Controls (DDEC)-Electronic Control Module (ECM) and Hewlett Packard data acquisition system. The enhanced model's results were compared to the steady state TTD (top tank differential) data.

The purpose of this research was to study the pressure drop profiles and regeneration temperature characteristics of Silicon Carbide (SiC) filters with and without a copper-based additive in the fuel, and also to compare their performance with two cordierite traps designated as EX-47 and EX-80. The collection of the particulate matter inside the trap imposes a backpressure on the engine which requires a periodic oxidation or regeneration of the particulate matter. The presence of copper additive in the fuel reduces the particulate ignition temperature from approximately 500 to 375°C. Two SiC systems were tested during this research. The first system consisted of one 14 L SiC trap, while the second system, the dual trap system (DTS), consisted of two 12 L SiC traps mounted in parallel. The test matrix included two types of regeneration tests, controlled and uncontrolled and three levels of Cu fuel additive (0, 30, and 60 ppm).

The purpose of this study was to investigate the pressure drop and regeneration characteristics of a silicon carbide (SiC) wall-flow diesel particulate filter. The performance of a 25 μm mean pore size SiC dual trap system (DTS) consisting of two 12 liter traps connected in parallel in conjunction with a copper (Cu) fuel additive was evaluated. A comparison between the 25 μm DTS and a 15 μm DTS was performed, in order to show the effect of trap material mean pore size on trap loading and regeneration behavior. A 1988 Cummins LTA 10-300 diesel engine was used to evaluate the performance of the 15 and 25 μm DTS. A mathematical model was developed to better understand the thermal and catalytic oxidation of the particulate matter. For all the trap steady-state loading tests, the engine was run at EPA mode 11 for 10 hours. Raw exhaust samples were taken upstream and downstream of the trap system in order to determine the DTS filtration efficiency.

The goals of this research are to understand the regeneration process in ceramic (Cordierite) monolith traps using a copper fuel additive and to investigate the various conditions that lead to trap regeneration failure. The copper additive lowers the trap regeneration temperature from approximately 500 °C to 375 °C and decreases the time necessary for regeneration. Because of these characteristics, it is important to understand the effect of the additive on regeneration when excessive particulate matter accumulation occurs in the trap. The effects of particulate mass loading on regeneration temperatures and regeneration time were studied for both the controlled (engine operated at full load rated speed) and uncontrolled (trap regeneration initiated at full load rated speed after which the engine was cut to idle) conditions. The trap peak temperatures were higher for the uncontrolled than the controlled regeneration.

The objective of this research was to obtain diesel particle size distributions from a 1988 and a 1991 diesel engine using three different fuels and two exhaust control technologies (a ceramic particle trap and an oxidation catalytic converter). The particle size distributions from both engines were used to develop models to estimate the composition of the individual size particles. Nucleation theory of the H2O and H2SO4 vapor is used to predict when nuclei-mode particles will form in the dilution tunnel. Combining the theory with the experimental data, the conditions necessary in the dilution tunnel for particle formation are predicted. The paper also contains a discussion on the differences between the 1988 and 1991 engine's particle size distributions. The results indicated that nuclei mode particles (0.0075-0.046 μm) are formed in the dilution tunnel and consist of more than 80% H2O-H2SO4 particles when using the 1988 engine and 0.29 wt% sulfur fuel.

This research quantifies the effects of a copper fuel additive on the regulated [oxides of nitrogen (NOx), hydrocarbons (HC) and total particulate matter (TPM)] and unregulated emissions [soluble organic fraction (SOF), vapor phase organics (XOC), polynuclear aromatic hydrocarbons (PAH), nitro-PAH, particle size distributions and mutagenic activity] from a 1988 Cummins LTA10 diesel engine using a low sulfur fuel. The engine was operated at two steady state modes (EPA modes 9 and 11, which are 75 and 25% load at rated speed, respectively) and five additive levels (0, 15, 30, 60 and 100 ppm Cu by mass) with and without a ceramic trap. Measurements of PAH and mutagenic activity were limited to the 0, 30 and 60 ppm Cu levels. Data were also collected to assess the effect of the additive on regeneration temperature and duration. Copper species collected within the trap were identified and exhaust copper concentrations quantified.

Studies have been conducted at Michigan Technological University (MTU) for over twenty years on methods for characterizing and controlling particulate emissions from heavy-duty diesel engines and the resulting effects on regulated and unregulated emissions. During that time, control technologies have developed in response to more stringent EPA standards for diesel emissions. This paper is a review of: 1) modern emission control technologies, 2) emissions sampling and chemical, physical and biological characterization methods and 3) summary results from recent studies conducted at MTU on heavy-duty diesel engines with a trap and an oxidation catalytic converter (OCC) operated on three different fuels. Control technology developments discussed are particulate traps, catalysts, advances in engine design, the application of exhaust gas recirculation (EGR), and modifications of fuel formulations.

In this study, the effects of an oxidation catalytic converter (OCC) on regulated and unregulated emissions from a 1991 prototype Cummins I.10-310 diesel engine fueled with a 0.01 weight percent sulfur fuel were investigated. The OCC's effects were determined by measuring and comparing selected raw exhaust emissions with and without the platinum-based OCC installed in the exhaust system, with the engine operated at three steady-state modes. It was found that the OCC had no significant effect on oxides of nitrogen (NOX) and nitric oxide (NO) at any mode, but reduced hydrocarbon (HC) emmissions by 60 to 70 percent. The OCC reduced total particulate matter (TPM) levels by 27 to 54 percent, primarily resulting from 53 to 71 percent reductions of the soluble organic fraction (SOF). The OCC increased sulfate (SO42-) levels at two of the three modes (modes 9 and 10), but the overall SO42- contribution to TPM was less than 6 percent at all modes due to the low sulfur level of the fuel.

The effects of fuel sulfur concentration on heavy-duty diesel emissions have been studied at two EPA steady-state operating conditions, mode 9 (1900 RPM, 75% Load) and mode 11(1900 RPM, 25% Load). Data were obtained using one fuel at two sulfur levels (Low Sulfur, LS = 0.01 wt% S and Doped Low Sulfur DS = 0.29 wt% S). All tests were conducted using a Cummins LTA10-300 heavy-duty diesel engine. No significant changes were found for the nitrogen oxides (NOx), soluble organic fractions (SOF) and XAD-2 (a copolymer of styrene and divinylbenzene) organic component (XOC) due to the fuel sulfur level increase at either engine mode. The hydrocarbon (HC) levels were not significantly affected by sulfur at mode 9; however, at mode 11 the HC levels were reduced by 16%. The total particulate matter (TPM) levels increased by 17% at mode 11 and by 24% at mode 9 (both significantly different).

Diesel exhaust particle size distributions were measured using an Electrical Aerosol Analyzer (EAA) with both conventional (0.31 wt. pet sulfur) and low sulfur fuel (0.01 wt pet sulfur) with and without a ceramic diesel particle filter (DPF). The engine used for this study was a 1988 heavy-duty diesel engine (Cummins LTA10-300) operated at EPA steady-state modes 9 and 11. The particle size distribution results indicated the typical bi-modal distribution; however, there were clear differences in the number of particles in each mode for all conditions. For the baseline conditions with no DPF, there was more than one order of magnitude greater number of particles in the nuclei mode for the conventional fuel as compared to the low sulfur fuel, while the accumulation modes for each fuel were nearly identical.